Seeing Below the Surface of Solar Cells

Method could help scientists learn new ways to boost photovoltaic efficiency.

Image courtesy of Molecular Foundry, Berkeley Lab

The Science

It’s difficult to improve processes you can’t see. That’s the problem for solar cells made of super-thin films. These highly flexible cells aren’t as efficient as they could be at converting sunlight to electricity. A team of Molecular Foundry scientists and industry users developed a way to “see inside” thin-film solar cells. They can see the subsurface realm—where much of the energy-conversion action happens. This imaging technique lets them map the cells in three dimensions during operation as they absorb sunlight.

The Impact

This unique tool will enable the solar industry to more rapidly develop reproducible high-efficiency solar cells. The tool provides a 3-D map of how photons interact with the material to make electricity to identify obstacles that dampen the efficiency of solar cells. The tool offers images with a resolution at the micron scale, or approximately one hundredth the diameter of a human hair.

Summary

Next-generation solar cells made of super-thin films of semiconducting material hold promise because they’re relatively inexpensive and flexible. Dramatically increasing the efficiency of thin-film solar cells is a tough challenge, partly because a solar cell’s subsurface realm—where much of the energy-conversion action happens—is inaccessible to real-time, nondestructive imaging. Scientists from the Molecular Foundry have developed a way to use optical microscopy to map—with micron resolution—thin-film solar cells in three dimensions as the cells absorb photons. The method uses a highly focused laser beam of infrared photons that penetrates inside the photovoltaic material. When two low-energy photons converge at the same pinpoint, there’s enough energy to excite electrons. These electrons can be tracked to see how long they last in their excited state and the obstacles they encounter, including grain boundaries and substrate interfaces. Long-lifetime electrons appear as bright spots in microscopy images. In a solar cell, long-lifetime electrons are more likely to result in electrical current. In addition, the imaging tool can create a 3-D map of a solar cell’s entire optoelectronic dynamics. So far, scientists have used the technique to better understand why adding a specific chemical to solar cells made of cadmium telluride—the most common thin-film material—improves the solar cells’ performance.

Contact

Jim Schuck
Molecular Foundry, Berkeley Lab
PJSchuck@lbl.gov; 510.486.4822

Funding

This work was partially performed at the Molecular Foundry, Lawrence Berkeley National Laboratory, and was supported by the Office of Science, Office of Basic Energy Sciences, Scientific User Facilities Division, of the U.S. Department of Energy (DOE) under contract DE-AC02-05CH11231. The work at the National Renewable Energy Laboratory was supported by the DOE, Office of Energy Efficiency and Renewable Energy (EERE), under contract DE-AC36-08GO28308. This material is based upon work supported by DOE under award DE-EE0005953. E.S.B. was supported by a DOE EERE SunShot Postdoctoral Research Award.

Publications

E.S. Barnard, B. Ursprung, E. Colegrove, H.R. Moutinho, N.J. Borys, B.E. Hardin, C.H. Peters, W.K. Metzger, and P.J. Schuck, “3D lifetime tomography reveals how CdCl₂ improves recombination throughout CdTe solar cells.” Advanced Materials 29(3), 1603801 (2017). [DOI: 10.1002/adma.201603801]